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I have heard a few good things about a Rustoleum kit for refinishing laminate counters and sinks. There is a reference here, and some other suggestions:
personally as a tile contractor I would go a different route as these kits run $200 bucks or so....and when you are done its still "just a paint job"
I would either go with a ready made sink / granite top ...like this
or do some custom tile work. I have done a number of those over the years. Surprisingly the new granite top with the pre-installed sink cost a bit LESS than the paint kit and from and install and durability perspective, is much easier to go from A to B.