Any ideas for painting gold on a white surface?
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Don't know exactly what you have in mind, but this is three projects in which gold paint was used on white.
http://www.hometalk.com/diy/paint/stenciled-walls-strike-gold-10182205
http://www.hometalk.com/diy/home-office/furniture/diy-map-desk-with-metallic-gold-paint-painted-furniture-9710900
http://www.hometalk.com/diy/decorate/rooms/gold-painted-bowl-2931469
Stenciled Walls Strike Gold
DIY Map Desk With Metallic Gold Paint
Gold Painted Bowl
Yes, paint it with black primer first. The black primer at Wally World is a great way to get the GOLD to stick. Flat Black spray paint actually eats into the older paint and because it is flat, the gold which is shiny by nature sticks better and won't chip off.