How to clean hard water toilet ring
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Use a pumice stone
Plunge down the water, then apply Barkeepers Friend. Let sit for about an hour, scrub and flush. If the stain is still there, get a product called THE WORKS and use that. It's fantastic. But so is BF.
I know this sounds crazy but I have heard that Tang breakfast drink will remove this if left to sit over night.
The Woks is great, only hard to find in some areas; check on-line and order it.
i use a pumis stone, works great
try pouring a liter or 2 of coke in the bowl and let sit over nite at least..
Here's a great article on removing hard water stains from a toilet.