What is the best substance to remove hard water stains in a toilet .
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Pumice stone....Pumie Stone bought at Ace Hardware or any hardware store.
Vinegar is good ....
https://www.youtube.com/watch?v=uQW3VE0q_nA
We use 2 cups of white vinegar the night before and let it set all night, then scrub it off the next morning. If it is real bad, repeat the process. It will all come off eventually. We also use Mr. Clean Magic toilet brush scrubber after the white vinegar.
I use IRON OUT
plain coke a cola
Try a product called 'Scouring Stick'. It's pumice.