How to paint rusty Electric Baseboard Heaters?

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My house is 30 years old and has electric baseboard heaters. Some of them have gotten pretty rusty and I want to take them out, sand the rusted areas and repaint them. Has anyone tried repainting them? Would Rustoleum's "HIGH HEAT" spray paint work for this? The heaters are made of steel. Would I need to PRIME them first? Is there a high heat primer available? Thanks so much!! :)

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