How do I make an ant spray?
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https://www.treehugger.com/lawn-garden/8-natural-homemade-insecticides-save-your-garden-without-killing-earth.html
Diluted original blue Dawn dishliquid kills ants quickly and helps to prevent them from returning for a time. Very cheap, easy, and very low toxicity compared to commercial chemical preparations for bug killer.
No need to spray, just open a package of Jirry corn muffin mix and sprinkle it where the ants are outside. If they are entering your home and coming into the kitchen, sprinkle it outside of your kitchen window or door. They take it back to their colony and it wipes them out.