What is a good natural weed killer.
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Boiling water, Epsom salt with boiling water, vinegar!
Salt water!
Watch using the vinegar and salt. They will alter the soil nutrition and you may have trouble getting anything to grow in that spot until it is amended or enough time elapses, they will also kill any thing that it touches on the leaves or by leaching into the roots in the soil. Salt is also very bad for the environment. It is changing the salinity of all the fresh bodies of water and also some areas are having problems with high salinity in drinking water. Water treatment plants aren't set up to deal with the higher salinity, so it gets into the drinking water.
Try vinegar in a spray bottle. It also kills grass so be careful.
A garden hoe and elbow grease, a roto tiller, and mulching controls weeds even can use layers of newspaper and cardboard or landscape fabric to control weeds
There are several here on HM:
https://www.hometalk.com/search/posts?filter=weed%20killer
I just soak the area and pull the next day...I need the exercise! LOL
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1 gallon white vinegar and 1 cup salt and 1 tablespoon liquid dish soap Combine ingredients in
spray bottle and treat weeds at the hottest time of day for best results.