I'm Desparate for a natural cleaner
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Try using vinegar and Dawn dish soap, or baking soda and lemon Juice, or Borax cleaner. Might need to scrub gently several times , rinse well.
Lemon juice is acidic, and when mixed with salt to make a paste, removes rust stains from fabrics, so I would give that a try! I'd let it sit a few minutes, then rub with a soft cloth.
I concur with the others, lemon juice, baking soda, vinegar, hydrogen peroxide ( not necessarily mixed ) and dawn are what I use and we have very hard water that leaves stains. Ammonia works but is strong smelling and cannot be mixed with bleach without causing a toxic gas. Always be careful when using and mixing with bleach.
I am a fan of baking soda
I would use baking soda and lemon juice to get rid of stains and then steam clean for a beautiful finish.
Have you ever tried Descaler from Norwex?