How do I know when to use white or apple cider vinegar
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It depends on what you are doing. What exactly are you using the vinegar for?
Well, white vinegar is distilled from grains. Its low price, relatively high acidity level, and clarity (no stains) make it an ideal cleaner. Apple cider vinegar is made from apples.
Typically to clean or to kill unwanted vegetation - white vinegar at 5% acidity is what is called for.
I always use white.
White -- apple cider vinegar has a lot of uses, but it costs a little more and I wouldn't waste it in the garden.