How can I remove a coffee stain from a white shirt after dry cleaning
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Dry cleaner should have been able to remove it....take it back and ask them.
Try blotting it with a bit of dishwasher detergent mixed with warm water. That should help lift the stain.
https://www.hunker.com/13421657/old-coffee-stain-removal
If it's really white, and the dry cleaner has done all he/she can, try a little straight bleach on a q-tip. Then wash as usual. And if it's not really a true white, and you've exhausted other methods to no avail, give the bleach a try anyway. Whatever dye is in the shirt may stick in the shirt better than the coffee.