How to paint a rusted free standing coat rack?
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This very helpful article will guide you through the process - https://www.krylon.com/how-to/faqs/product/can-i-spray-paint-over-rust.jsp
Clean it well removing the rust, then paint it with a paint made especially for metal. There are many different metal spray paints.
Sand it off lightly to remove any loose or peeling areas, wipe down with pure vinegar and then spray paint with a metal paint such as Rustoleum.