I have a gas fireplace that has gold metal trim insert .
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http://www.hometalk.com/diy/living-room/fireplaces-mantels/update-your-brass-fireplace-trim-and-outdated-fireplace-tile-14911768
Update Your BRASS Fireplace Trim and Outdated Fireplace Tile
we just updated ours and used the rust-oleum hi-heat flat black spray paint shown in the video above. cover everything around it with tape and paper. make sure you have ventilation but not so much that it affects the spray. looks great! 8^)
eThere is a product called high heat spray paint. I just Googled it and there are lots of options. You'd need to tape off everything you don't want painted though. I painted my metal wall heaters and they look great