Paint exposed fireplace flue?
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There is stove pipe paint made specifically for painting stove pipe. Can handle from 1000 to 2000 degrees. Yes you can paint the brass. Many people had complete brass doors and painted them. Use the high heat paint on them.
https://www.amazon.com/Duravent-High-Temperature-Paint-Stove/dp/B006BKLKW0
how about building a box around the pipe. Paint the inside with high heat paint. Then you can paint the wood.
Please consider specality fireplace paints.
https://www.efireplacestore.com/paint.html