What is the best way to seal a wine barrel wanting to be a pond?
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Try Thompson Wood Sealer
The easiest way would be to buy a plastic liner made for that purpose.
rather than trying to seal it, purchase a pond liner material or roof membrane to line the barrel....add water and plants, dont add fish right away let the plants and water settle for a couple of weeks
https://www.doityourself.com/stry/wine-barrel-pond-to-seal-or-not
Is Flex Seal non-toxic?
Why not use heavy pond liner? Guaranteed no leak and no leaking of possible toxins in the water.
Flex seal
All the barrel ponds I have ever seen had a liner in them to protect the wood and prevent water leakage. You can buy liner material made for ponds. Or you could try using 6 to 20 mil plastic sheeting or crawl space vapor barrier. Use black, not clear or translucent. fold and shape it to the inside of the half barrel. Staple the edges along the upper edge to hold it in place.