What cleans off baked on cooking spray for Pyrex
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baking soda or bar keepers friend
https://www.leaf.tv/articles/how-to-remove-baked-on-cooking-spray-from-pans/
Make a paste of baking soda and water, apply it to the spots of baked on cooking spray, let it sit overnight, take a scrubber to it, may need to repeat until clean.
SOS and lots of elbow work.
I spray with oven cleaner and use a round plastic scrubby when it won't come off. Now I don't use the spray much anymore, just use a paper towel and olive oil.
Try Bon Ami, or Barkeeper's Friend.
All I do is put really hot soapy water in it and let it soak and scrub it with the scrubber side of a sponge while it is still hot. That usually works for me.
I hv actually used a steelwool soap pad...