How do I remove rust from sidewalk?
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Pour or spray white vinegar on the rusted surface in place of lemon juice for tougher stains. Let the vinegar sit for several minutes before scrubbing it with a wire brush. Rinse away the rust with some cold water and repeat for difficult stains. Scrub the surface of the concrete with a brush.
https://www.youtube.com/watch?v=50SgAnJXpuc
The Works toilet bowl cleaner (original this one) If it doesn't work you've spent $2 for extra cleaner.
Here's a great hometalk post on removing rust stains from concrete.