How can I separate a living room/dining room area with paint?
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Do you have any photos of the room?
It is much easier to look at these examples then to try and explain it. Hope this helps.
https://www.homedit.com/how-to-separate-two-rooms-sharing-the-same-walls-with-paint/
You could put a decorative piece of trim painted the same color as the wall and window trim, between the two paint colors.
You can see in this photo that even just the way you lay out your furniture can help to divide a room in 2. Face your sofa away from the dining area, and use a buffet as a divider as well.