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Yes of course,
Tips: See the material of the shades before buying the perfect paint. The best paint is the one that is designed for specific material of your lamp shade.
Example: shades that are made of fabric, then fabric paint is the right companion. Metal, Glass, and ceramic lampshades will look excellent with the enamel paint.
Source: Paint types for Lamp Shade
I have used a "wash" technique on many lampshades over the years. Watered down paint and rewashing until you get the darkness you want. Be sure to work where the shade can be held up off the bottom edge so the water can drip off freely as it dries..
Watered down Chalk Paint or Emulsion sample pot watered down.