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Not sure what kind of clasp. But a little cooking oil or WD40 on the clasp should work.
if the oil doesn't work it's probably caked with gunk put some Dawn dish soap on it and use a toothbrush then start trying to open it slowly working it back & forth. what kind of clasp is it ? Lobster claw,circle/oring,spring ring clasp? if it is not soldered you could always gently bend it(clasp) open and slide the clasp off of chain then put it back on/together.