What can remove stubborn hard water deposit from bathtub?
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The works cleaner or CLR is what I have found to be the best.
Try soaking cotton wool in lemon juice and placing it over the stain and covering over with plastic bag ,leave it to soak over night rinse next morning, good luck !
Try using a scouring stick, available at Lowe's or Home Depot. These pumice sticks work great on tubs, sinks, and toilets.
I know that this involves chemicals, but needs must. My magic combo is Lime-Away and the pumice stick. Our water is as hard as concrete. Once I got rid of the hard water stains, I maintain with Lime-Away once/week hand haven't had a problem.