Grout in shower drain
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http://handypro-handyman.blogspot.com/2012/03/how-do-you-get-rid-of-black-mold-on.html
just simply spray it with clorox. and let it sit for awhile, then rinse
Straight vinegar. Let it sit a few minutes and scrub with a stiff brush.
Start with pulling the drain cover off, and clean with a mold and mildew cleaner, spray the drain also. Follow the directions on the bottle, how long to wait and rinse.
Baking soda and vinegar
Glad to help.
Sounds like mildew. Bleach spray . But make sure you Wear old clothing. Take down the shower curtain, rugs etc. Open the window to protect yourself form the fumes. Let the bleach sit for 30 minutes. Rinse well when you are complete. Do NOT mix anything with it . You can produce a noxious fume that can hurt your lungs and require hospitalization.