How to stop a dog from urinating?

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We just moved into our new home. We have a male dog (Chihuahua-Terrier) mix, and I can't stop him from urinating inside our home. I have tried Vinegar, baking soda-mixed w/vinegar, and plain soap and water to clean. They say this should clear the smell, and stop them from urinating in the house. Guess what, it doesn't! Does anyone have any suggestions, as to what to use? I don't want to get rid of the dog, he belongs to my daughter who left to college (I'm close to giving him away). Their is a doggie door to come and go, but is only doing this @ night. Please help! Feeling desperate. Thanks

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