How do I remove urine build up on toilet?
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Clean it. I use vinegar. If it is stained on the toilet seat, consider purchasing a new one. A decent one can be had at any hardware or home improvement center for less than $20.
Habitat for Humanity in Minnesota has toilet seats for $5 or a whole toilet for $20
You can use baking soda and vinegar or bleach.
Lysol toilet bowl cleaner in a black squirt bottle applied with a Mr. Clean Magic Eraser. It worked better than bleach did for me.
Bleach-based powder cleanser like Comet works great. Dampen the surface sprinkle, let stand a few minutes. Using a microfibre cloth scrub the surface and rinse. The bleach and the powder should get out most stains.