How can I remove stains around my shirt collars?
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Measure out your liquid detergent and pour a little of it straight on the collar ring then wash as usual.
Spray with Shout Advanced, let it sit for a day and then wash
Shampoo applied to damp collar and rub.
https://www.wikihow.com/Remove-Stubborn-Ring-Around-the-Collar
I spray my laundry with Young Living's Thieves cleaner then wash with Thieves Laundry Detergent
I use a bar of fels naptha. Wet the soap and lather it directly on the stain before laundering.