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Hello. I would mix 50/50 of vinegar and water in a spray bottle. Then spray it on heavily and let it sit for 5-10 minutes. Then use a scrub brush and scrub. Repeat if necessary. Then mop the floors clean.
http://homeguides.sfgate.com/remove-hard-water-scale-painted-surfaces-29869.html
I would use a gallon of vinegar and a gallon of water in a bucket and soak hand towels to lay over stains, so it stays wet. Wait an hour, then wipe up. Vinegar won't hurt the towels, just rinse them with a hose, wring out and throw in washer. The longer it stays on the easier it comes up.
I would use vinegar and water, but I might repaint it also