What can remove stubborn hard water deposit from bathtub?
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Try soaking cotton wool in lemon juice and placing it over the stain and covering over with plastic bag ,leave it to soak over night rinse next morning, good luck !
Try using a scouring stick, available at Lowe's or Home Depot. These pumice sticks work great on tubs, sinks, and toilets.
I know that this involves chemicals, but needs must. My magic combo is Lime-Away and the pumice stick. Our water is as hard as concrete. Once I got rid of the hard water stains, I maintain with Lime-Away once/week hand haven't had a problem.