What is thd best was to remove dark red wine stains from 100% polo shi
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If the garment has not yet been washed, try pouring white wine over the spot. Yes, white wine.
https://www.lacrema.com/remove-red-wine-stains/
https://www.realsimple.com/home-organizing/cleaning/cleaning-stain-removal/remove-red-wine-stain
Try 4 cups water, 1/4 cup vinegar and 1 tablespoon dish liquid. Soak for a while, say at least 15 minutes.