How do I clean stubborn stains in my shower?
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if it's a fiber glass unit, the surface is / may have been damaged by repeated use of abrasive cleaners or scrubby pads ... https://www.hunker.com/13416719/how-to-remove-scratches-from-fiberglass
It that on the floor or walls?
If tile, I use Tilex and a scrub brush .
Unless it's marble, I would recommend "wet & forget shower". It's a no scrub product that will take a couple of weeks to clean but it will also keep it clean. It's the only thing that got my textured floor clean. Available at QVC, Lowe's, or walmart.com.
Another idea would be to use Mr. Clean Magic Eraser and white vinegar.
For super stubborn, try "Heavy Duty Scouring Stick".
Both the stick & eraser worked on mine but the texture "ate them up" . Also, the results were only temporary. Wet & Forget even keeps my glass shower doors clean.
If it's stained with calcium, lime and rust I use CLR. Just dilute CLR with water. Put in spray bottle and spray stains. Let set for awhile, then whipe down with rag or sponge. Rinse well.