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Hi Carlene, sorry you broke your picture frame. Be safe working with shatter glass. Be sure to wear gloves so you won't cut yourself. Hope this is helpful. Remove the back and the picture and set them aside. If the picture has any glass that is stuck to it, you can use a hairdryer to heat up and loosen the hold between the two. Extract all of the broken glass. Carefully get all of the glass out of the frame.
How to Replace Broken Glass in a Picture Frame: 9 Steps
https://www.wikihow.com/Replace-Broken-Glass-in-a-Picture-Frame
Carlene,. Place the picture frame over some newspaper and remove carefully with paper towel or some thick gloves. Then put it in a jar if you can for recycling. Aloha!
Take it outside and put it on a dropcloth, use gloves and needle nose pliers to protect your hands.