How to kill weeds with a solution?
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Natural ways to kill weeds: boiling water; Epsom salt followed by boiling water; vinegar. Method depends on location.
I started using this last year with success:
https://www.hometalk.com/diy/outdoor/pest-repeller/natural-weed-killer-20665086
Natural Weed Killer
Just make sure to never pour the salt mixture on soil, as the solution will make sure that nothing grows in that spot again.
Whatever recipe you use (I simply use vinegar) put it in this!
https://www.homedepot.com/p/HDX-1-Gal-Sprayer-1501HDXA/307766754